Last Updated: September 24, 2026

Details for Patent: 5,202,128


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Summary for Patent: 5,202,128
Title:Sustained release pharmaceutical composition
Abstract:The present invention relates to a pharmaceutical pellet composition having a core element including at least one highly soluble active ingredient and a core coating which is partially soluble at a highly acidic pH. The pharmaceutical composition provides a slow release of active ingredient at a highly acidic pH and provides a constant, relatively faster rate of release at a more alkaline pH such as that of the intestine. Oral administration of the pharmaceutical pellet composition of the present invention to a patient is effective to deliver to the blood levels of active ingredient within the therapeutic range and to maintain such levels over an extended period of time.
Inventor(s):Angelo M. Morella, Mark C. Fisher
Assignee: Alpharma Pharmaceuticals LLC
Application Number:US07/574,551
Patent Claim Types:
see list of patent claims
Use; Composition; Formulation; Dosage form;
Patent landscape, scope, and claims:

US Patent 5,202,128: Scope, Claim Construction, Expiration, and Pharmaceutical Patent Landscape

US Patent 5,202,128 covers multiparticulate, pH-dependent sustained-release pellets. Its central technical concept is a coating that combines an insoluble rate-controlling polymer, an enteric polymer, and an acid-soluble material. The coating is designed to begin releasing drug slowly in the stomach and release it faster after exposure to the higher pH of the intestine.

The patent was directed particularly to highly water-soluble active ingredients, including morphine salts, and to 8-to-24-hour pain-treatment regimens. The patent issued on April 13, 1993, and its 17-year patent term expired in April 2010, subject to any applicable patent-term adjustment or terminal disclaimer. It therefore does not presently provide enforceable US exclusionary rights. [1][2]

What does US Patent 5,202,128 protect?

The patent protects a formulation architecture rather than a single drug molecule. The independent claims require a core pellet containing an active ingredient and a multipart coating with three functional components:

Component Required function General claim range
Matrix polymer Insoluble from pH 1 to 7.5 and controls release At least 35%
Enteric polymer Substantially insoluble at pH 1 to 4 and soluble at pH 6 to 7.5 1% to 30%
Acid-soluble compound Permits release initiation in the stomach 1% to 60%

The percentages for claims 1, 10, 18, 24, 25 and 26 are calculated against the combined weight of the three coating components. The claims also require a functional release result: release must begin slowly in the stomach and proceed at a faster rate in the intestine.

The broadest formulation claims are claims 1 and 10. Claim 1 covers a composition with a highly water-soluble active ingredient. Claim 10 narrows the active ingredient to an acid-addition salt of morphine. Claim 11 further limits the morphine salt to morphine sulfate.

The patent’s scope is therefore defined by four linked requirements:

  1. A pellet or multiparticulate core.
  2. A therapeutically effective amount of an active ingredient.
  3. A three-part pH-responsive coating.
  4. A specified stomach-to-intestine release relationship.

A formulation that merely contains ethyl cellulose and an enteric polymer would not necessarily fall within the claims. The acid-soluble component and the claimed functional release behavior are central limitations.

How do the independent claims differ?

The independent claims fall into three principal groups.

Composition claims for soluble drugs

Claim 1 covers a pH-dependent sustained-release pellet containing an active ingredient with aqueous solubility of at least 1 part drug in 30 parts water. This is a relatively broad drug-class limitation. It reaches numerous pharmaceutical categories, including antihistamines, antibiotics, cardiovascular agents, analgesics and opiate agonists.

Claim 24 adds a narrower requirement that the matrix polymer be composed of specified polymers, including:

  • Ethyl cellulose.
  • Quaternary ammonium acrylic or methacrylic polymers.
  • Acrylic or methacrylic ester copolymers.
  • Mixtures of those materials.

Claim 24 is narrower than claim 1 because it expressly limits the matrix polymer to the listed polymer classes.

Morphine composition claims

Claim 10 covers the same three-component release system when the active ingredient is an acid-addition salt of morphine. Claim 11 specifies morphine sulfate.

Claims 25 and 17 narrow the polymer and coating composition further. Claim 17, as supplied, contains a dependent-claim reference error to claim 49. The issued patent text should control over the provided transcription when evaluating enforceability or prosecution history. The substantive limitation recites a coating containing:

Coating constituent Claimed range
High-molecular-weight polyethylene glycol, molecular weight 1,700 to 20,000 15% to 40%
Ethyl cellulose 45% to 65%
Methacrylic acid:acrylic acid ethyl ester 1:1 copolymer 4% to 20%

This narrow combination is more relevant to product-specific comparison than the broad genus in claim 10.

Method-of-treatment claims

Claim 18 covers treatment of pain using the claimed pH-dependent pellet composition. Claims 19 through 23 narrow the method to acute or chronic pain and morphine acid-addition salts.

Claim 20 specifies a unit dosage form administered over an interval of approximately 8 to 24 hours. Claims 21 through 23 identify morphine salts, including morphine sulfate and morphine hydrochloride.

The method claims require both administration and use of a composition meeting the formulation limitations. They do not claim treatment with extended-release morphine generally.

What formulations are protected by the patent?

The patent identifies three coating technologies by function.

Matrix polymer

The matrix polymer remains substantially insoluble throughout the stomach and intestinal pH range. Its role is to maintain a diffusion barrier and regulate drug release. The disclosed candidates include ethyl cellulose and acrylic or methacrylic polymers.

Ethyl cellulose is particularly important because it creates a water-permeable but insoluble film. Quaternary ammonium methacrylate polymers, such as commercially available Eudragit-type materials, can alter permeability and release rate.

Enteric polymer

The enteric polymer is intended to remain substantially insoluble in the stomach and dissolve or become substantially more permeable in the intestine. The claims list:

  • Cellulose acetate phthalate.
  • Hydroxypropyl methylcellulose phthalate.
  • Polyvinyl acetate phthalate.
  • Methacrylic acid/acrylic ester copolymers.
  • Hydroxypropyl methylcellulose acetate succinate.
  • Shellac.
  • Cellulose acetate trimellitate.

The enteric polymer does not perform the conventional function of completely preventing gastric release. The claims require sufficient gastric delay, but also require initiation of release in the stomach through the acid-soluble component.

Acid-soluble compound

The acid-soluble compound creates pores or channels as it dissolves in the stomach. The claim examples include:

  • Polyvinylpyrrolidone.
  • Hydroxypropyl cellulose.
  • Hydroxypropyl methylcellulose.
  • Polyethylene glycol with molecular weight of 1,700 to 20,000.
  • Polyvinyl alcohol and related monomers.

This component distinguishes the invention from a conventional enteric-coated dosage form. The intended profile is not "no release in the stomach, followed by release in the intestine." It is slow initial gastric release followed by faster intestinal release.

What are the key dependent-claim limitations?

Claims 5 through 9 and 12 through 17 add technical limitations that narrow infringement exposure.

Claim group Principal limitation
5 and 6 Gastric and intestinal dissolution profiles provide substantially equivalent bioavailability to immediate-release dosage forms; plasma fluctuations are minimized
7 Matrix polymer 35% to 75%, enteric polymer 2% to 20%, acid-soluble compound 15% to 50%
8 and 9 Plasticizer and filler options, with narrower coating ranges
12 Intestinal release rate is 1.2 to 3 times the gastric release rate
13 and 14 Reduced morphine plasma fluctuation and at least three hours at or above 75% of maximum concentration
16 Morphine coating ranges with acid-soluble compound at 15% to 40%
17 Specific polyethylene glycol, ethyl cellulose and methacrylic copolymer formulation

The functional limitations in claims 1, 10, 18, 24, 25 and 26 create potential claim-construction disputes. Terms such as "effective to allow," "slow rate," "faster rate," "therapeutically effective amount," and "predetermined interval" are dependent on formulation testing and the specification’s examples.

How strong was the patent estate?

The patent had meaningful historical breadth but limited present-day commercial strength because the patent expired in 2010.

Historical strengths

The patent’s strongest features were:

  • Coverage of a general multiparticulate pellet platform.
  • Specific coverage of highly soluble active ingredients.
  • Express morphine sulfate and morphine hydrochloride embodiments.
  • Method claims covering acute and chronic pain.
  • Broad polymer classes rather than a single commercial excipient.
  • Functional release requirements tied to gastric and intestinal pH.

The combination of composition and method claims would have increased litigation leverage during the patent term, particularly where a branded product used morphine pellets with ethyl cellulose, a methacrylic acid copolymer and polyethylene glycol.

Weaknesses and design-around opportunities

The estate also had technical vulnerabilities:

  • The claims require all three coating functions.
  • The active ingredient must meet the claimed solubility threshold in the relevant claims.
  • The coating must demonstrate the specified pH-dependent release behavior.
  • A formulation using a different release mechanism could avoid the claims.
  • A monolithic matrix tablet, osmotic system or non-pellet dosage form would present a stronger non-infringement position.
  • A formulation using a polymer outside the expressly listed classes could avoid the narrower claims.
  • Claims 12, 14 and related functional limitations would require comparative release or pharmacokinetic evidence.

The patent does not broadly claim all extended-release morphine products. It claims a particular multiparticulate coating system and, in the method claims, administration of that system.

When did US Patent 5,202,128 lose exclusivity?

The patent issued on April 13, 1993. For a US utility patent filed before June 8, 1995, the ordinary term was 17 years from grant, not 20 years from the earliest effective filing date. On that basis, the ordinary expiration date was April 13, 2010. [1][2]

Event Date
US patent grant April 13, 1993
Ordinary 17-year term April 13, 2010
Current enforceable status Expired
Current Paragraph IV risk from this patent None

The expiration date should be confirmed against the USPTO patent record, including any patent-term adjustment, terminal disclaimer or reexamination certificate. The supplied claim set does not identify a later enforceable continuation or reissue.

What was the Orange Book status of US Patent 5,202,128?

US Patent 5,202,128 should not be treated as a currently operative Orange Book patent. The Orange Book lists patents submitted by new drug application sponsors for approved products, and listing status is product-specific. A patent may cover a formulation concept without being listed for every product that uses the active ingredient. [3]

The patent is not a current barrier to an abbreviated new drug application based on its expired claims. It also does not create an active 30-month stay under Hatch-Waxman. A Paragraph IV certification against an expired patent would not produce the same litigation consequences as a challenge to an unexpired Orange Book patent.

For morphine sulfate extended-release products, the operative patent landscape has historically included product-specific formulation patents, manufacturing patents and later-generation controlled-release technologies. Those patents must be reviewed separately from US 5,202,128.

Which companies or products were most relevant to the patent?

The patent is technically aligned with sustained-release morphine products using coated pellets, including technologies historically associated with Napp Pharmaceutical Group and its affiliates. The morphine pellet concept is also relevant to products such as Zomorph outside the United States and to broader controlled-release morphine development.

The connection should not be overstated. A product containing extended-release morphine is not automatically covered. Product-specific analysis requires comparison of:

  • Pellet versus tablet architecture.
  • Morphine salt.
  • Coating polymers.
  • Polymer percentages.
  • Plasticizer and pore-former content.
  • Gastric and intestinal dissolution.
  • Dose interval.
  • Manufacturing process.

MS Contin, Kadian and other extended-release morphine products have used distinct formulation technologies and patent portfolios. Kadian, for example, is associated with extended-release morphine sulfate multiparticulate technology, but the relevant patent estate cannot be assumed to be identical to US 5,202,128. FDA product records and Orange Book listings must be reviewed by NDA and product presentation. [3][4]

What patent litigation and Paragraph IV challenges affected this patent?

The patent’s expiration eliminates current infringement litigation risk based solely on US 5,202,128. During its term, a generic applicant could have filed a Paragraph IV certification if the patent was listed against the relevant reference-listed drug. A Paragraph IV certification would have required a patent-specific analysis of validity, enforceability and infringement.

The principal attack vectors would have included:

  1. Anticipation: Earlier sustained-release pellets using insoluble polymers, enteric polymers and soluble pore-formers.
  2. Obviousness: Combining known ethyl-cellulose films, enteric polymers and water-soluble pore-formers.
  3. Written description: Whether the broad drug classes and polymer classes were adequately supported.
  4. Enablement: Whether the specification enabled the full range of polymer percentages and active ingredients.
  5. Indefiniteness: Interpretation of "slow rate," "faster rate," "substantially delay," and "effective" release relationships.
  6. Non-infringement: Absence of one coating component, failure to meet the solubility threshold or use of a different release mechanism.

No current Paragraph IV exposure remains from this patent because the claims are expired. The existence of historical litigation or settlement activity cannot be inferred from the claim text alone. The USPTO and PACER records would control for a complete docket history. [1][5]

How does the patent compare with later extended-release morphine patents?

US 5,202,128 is a platform patent. Later morphine patents generally became more product-specific.

Feature US 5,202,128 Later morphine formulation patents
Dosage form Coated pellets Pellets, tablets, capsules or multiparticulates
Drug focus Broad soluble actives, including morphine Often morphine-specific
Release mechanism pH-dependent three-component coating May use diffusion, osmotic release, matrix systems or multiparticulate beads
Key polymers Ethyl cellulose, enteric polymers, water-soluble compounds Product-specific polymer and processing combinations
Claim strategy Functional gastric/intestine release relationship Structural formulation, process and pharmacokinetic limitations
Current status Expired Depends on individual patent and term

The patent’s broad platform claims would have been most valuable before later products developed independent formulation barriers. Its present value is primarily freedom-to-operate history, prior-art relevance and technology provenance.

What manufacturing and intellectual-property barriers remain?

Although US 5,202,128 is expired, manufacturing barriers can remain under other rights and under regulatory requirements.

Relevant manufacturing variables include:

  • Pellet-core formation.
  • Drug layering or extrusion-spheronization.
  • Coating weight gain.
  • Polymer dispersion and plasticizer selection.
  • Uniformity of coating thickness.
  • Control of gastric and intestinal dissolution.
  • Scale-up of multiparticulate blends.
  • Capsule filling and dose uniformity.

A generic or follow-on manufacturer may avoid the expired patent but still face:

  • Later formulation patents.
  • Process patents.
  • Trademark and trade-dress restrictions.
  • Controlled-substance manufacturing requirements.
  • FDA bioequivalence requirements.
  • Product-specific safety and abuse-deterrence requirements.
  • Manufacturing know-how that is not disclosed in the expired patent.

For an ANDA, the central regulatory question is whether the proposed product is bioequivalent to the reference listed drug and whether all listed unexpired patents have been addressed. The expired status of US 5,202,128 removes one patent obstacle but does not resolve the complete regulatory or patent analysis. [3][4]

What generic launch risks exist today?

US 5,202,128 presents no current generic launch risk because it is expired. A launch assessment should instead focus on:

  • Unexpired Orange Book patents for the relevant morphine product.
  • FDA exclusivity periods.
  • Formulation and process patents owned by the reference-product sponsor.
  • Regulatory exclusivity attached to the NDA.
  • Controlled-substance supply and manufacturing capacity.
  • Product-specific labeling and abuse-deterrence requirements.

The patent may still be cited as prior art against later patents. Its disclosure of the three-component coating architecture could limit the ability of a later applicant to obtain broad claims covering the same combination.

What is the commercial significance of the patent?

The patent’s commercial significance was highest for sustained-release oral products containing highly soluble drugs, where a conventional insoluble matrix could release drug too quickly in the stomach or too slowly in the intestine.

For morphine, the claimed objective was to reduce plasma-concentration fluctuation while maintaining an extended dosing interval. Claims 12 and 14 quantify that objective by requiring a faster intestinal release rate and sustained plasma concentrations.

The patent no longer supports royalty collection or exclusion of competitors in the United States. Its continuing commercial relevance lies in:

  • Prior-art analysis.
  • Product provenance.
  • Historical valuation of controlled-release technology.
  • Freedom-to-operate reviews for new pellet products.
  • Assessment of later patents claiming similar polymer combinations.
  • Evaluation of overseas family members with different expiration dates or legal status.

Key Takeaways

  • US Patent 5,202,128 covers pH-dependent sustained-release pharmaceutical pellets.
  • The core invention combines an insoluble matrix polymer, an enteric polymer and an acid-soluble compound.
  • Morphine sulfate is specifically covered by claims 10, 11 and related dependent claims.
  • Claims 18 through 23 cover pain-treatment methods using the claimed pellet system.
  • Claims 12 and 14 add quantitative release and pharmacokinetic limitations.
  • The patent issued on April 13, 1993, and its ordinary term expired in April 2010.
  • It does not create a current US Orange Book or Paragraph IV barrier.
  • Extended-release morphine products must be analyzed against their own product-specific patent estates.
  • Later patents, FDA requirements and manufacturing barriers may remain commercially relevant.

FAQs

Is US Patent 5,202,128 still enforceable?

No. Its ordinary US patent term expired in April 2010, subject to confirmation of the official USPTO term record.

Does the patent cover all extended-release morphine sulfate products?

No. It covers morphine-containing pellet compositions that meet the specified three-component coating, polymer, percentage and release limitations.

Does morphine sulfate in a capsule infringe the patent?

Not necessarily. Capsule presentation alone does not determine infringement. The underlying pellets must satisfy the patent’s structural and functional limitations.

Can a generic rely on the patent’s expiration?

Yes. An expired patent cannot support a current infringement claim or a Hatch-Waxman 30-month stay. The generic must still address any other unexpired patents and FDA requirements.

Are the polymer percentages measured against the entire dosage form?

For the principal claims, the percentages are measured against the combined weight of components (a), (b) and (c), unless a claim separately specifies coating-based percentages for plasticizers or fillers.

References

  1. United States Patent and Trademark Office. (1993). U.S. Patent No. 5,202,128, pH-dependent sustained release pharmaceutical pellet composition.
  2. United States Patent and Trademark Office. (n.d.). Patent term calculator and patent term information. https://www.uspto.gov/patents/laws/patent-term-calculator
  3. U.S. Food and Drug Administration. (n.d.). Approved drug products with therapeutic equivalence evaluations: Orange Book. https://www.fda.gov/drugs/drug-approvals-and-databases/approved-drug-products-therapeutic-equivalence-evaluations-orange-book
  4. U.S. Food and Drug Administration. (n.d.). Drugs@FDA: FDA-approved drugs. https://www.accessdata.fda.gov/scripts/cder/daf/
  5. United States Courts. (n.d.). PACER case locator. https://pcl.uscourts.gov/

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Drugs Protected by US Patent 5,202,128

Applicant Tradename Generic Name Dosage NDA Approval Date TE Type RLD RS Patent No. Patent Expiration Product Substance Delist Req. Patented / Exclusive Use Submissiondate
>Applicant >Tradename >Generic Name >Dosage >NDA >Approval Date >TE >Type >RLD >RS >Patent No. >Patent Expiration >Product >Substance >Delist Req. >Patented / Exclusive Use >Submissiondate

Foreign Priority and PCT Information for Patent: 5,202,128

Foriegn Application Priority Data
Foreign Country Foreign Patent Number Foreign Patent Date
AustraliaPJ2192Jan 06, 1989

International Family Members for US Patent 5,202,128

Country Patent Number Estimated Expiration Supplementary Protection Certificate SPC Country SPC Expiration
Austria 133862 ⤷  Start Trial
Austria 167629 ⤷  Start Trial
Australia 4773290 ⤷  Start Trial
Australia 617573 ⤷  Start Trial
Canada 2007181 ⤷  Start Trial
Germany 69025208 ⤷  Start Trial
>Country >Patent Number >Estimated Expiration >Supplementary Protection Certificate >SPC Country >SPC Expiration

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