Last Updated: August 9, 2026

Claims for Patent: 8,765,451


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Summary for Patent: 8,765,451
Title:Method of treating an off-gas stream and an apparatus therefor
Abstract:The present invention provides a method of treating an off-gas stream (80) comprising NH3 and H2S to provide a sulphate stream (910), the method comprising the steps of: (i) providing a first off-gas stream (80) comprising NH3, H2S, CO2 and optionally one or more of HCN, COS and CS2; (ii) passing the first off-gas stream (80) to an incinerator (300) to oxidize NH3, H2S, and optionally one or more of HCN, COS and CS2 to provide a second off-gas stream (310) comprising N2, H2O, SO2 and CO2; (iii) scrubbing the second off-gas stream (310) with a first aqueous alkaline stream (380, 876 a) in a caustic scrubber (350) to separate SO2 and a part of the CO2 from the second off-gas stream to provide a spent caustic stream (360) comprising carbonate and one or both of sulphite and bisulphite and a caustic scrubber off-gas stream (370) comprising N2 and CO2; and (iv) passing the spent caustic stream (360) to an aerator (900) comprising sulphur-oxidizing bacteria in the presence of oxygen to biologically oxidize sulphite and bisulphite to sulphate to provide a sulphate stream (910).
Inventor(s):Sandra Schreuder
Assignee: Shell USA Inc
Application Number:US13/263,146

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